Efficient Borylation of Reactive Aryl Halides with MPBH (4,4,6-Trimethyl-1,3,2-dioxaborinane)

[摘要]：The combination of 4,4,6-trimethyl-1,3,2-dioxaborinane, a particularly stable and inexpensive borylation reagent, and Buchwald's palladium catalyst provides a simple, fast, cost-effective borylation of electron-rich, reactive iodides, bromides, and tri-flates to produce stable, easily purified boronic esters.

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