Facile Catalytic SNAr Reaction of Nonactivated Fluoroarenes with Amines Using eta(6)-Benzene Ruthenium(II) Complex

[摘要]：Catalytic SNAr reaction of fluoroarenes possessing no electron-withdrawing group(s) with cyclic amines was achieved using a readily accessible Ru catalyst, which was prepared from [Ru(benzene)Cl-2](2), AgOTf, and P(p-FC6H4)(3). The coexistence of molecular sieves MS4A realized high conversion and various substituted aryl amines were obtained in good to high yields.

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