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Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

  作者 PAUL NANDA D; KRAEMER TOBIAS; MCGRADY JOHN E; GOSWAMI SREEBRATA  
  选自 期刊  Chemical Communications;  卷期  2010年46-38;  页码  7124-7126  
  关联知识点  
 

[摘要]The isolation, structural chracterisation and electronic structure of a formally mixed-valent Rh(-I)-Rh(III) complex is described, along with its reaction with dioxygen leading to double arene hydroxylation of the coordinated ligands.

 
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