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Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis

  作者 BRICOUT HERVE; BANASZAK ESTELLE; LEN CHRISTOPHE; HAPIOT FREDERIC; MONFLIER ERIC  
  选自 期刊  Chemical Communications;  卷期  2010年46-41;  页码  7813-7815  
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[摘要]Water-soluble phosphanes were tagged with a light-responding diazo group. Upon UV exposure, the diazo-isomerisation led to phosphane morphology change, resulting in an increase in the reaction rate of an aqueous palladium-catalysed cleavage reaction.

 
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