Pd-0-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-alpha-chloroacrylates

[摘要]：A novel and fully chemo-and stereoselective three component strategy leading to Z-alpha-chloroacrylates by a Pd-0-catalyzed reaction of CO (1 atm) with 1,1-dichloro-1-alkenes and various alcohols is disclosed. This catalytic approach compares favourably with the Wittig type strategies as alpha-chloroacrylates of pure Z configuration are obtained in high yield.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内