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When chiral product and catalyst are the same: discovery of asymmetric organoautocatalysis

  作者 TSOGOEVA SVETLANA B  
  选自 期刊  Chemical Communications;  卷期  2010年46-41;  页码  7662-7669  
  关联知识点  
 

[摘要]The process of asymmetric organoautocatalysis appears to be a natural extension to asymmetric organocatalysis, and holds implications for models on the origin of biological homochirality. The discovery of asymmetric organoautocatalysis (i.e. the process in which the chiral product of a purely organic reaction acts as an organocatalyst for its own formation under conservation of its absolute configuration) and more recent reports on related systems are discussed in this review.

 
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