Chain mechanism for exchange of D-2 with a ruthenium hydride

[摘要]：The ruthenium hydride of (Ar4CpOH)Ru(CO)(2)H exchanges cleanly and rapidly with D-2 at room temperature to generate the ruthenium deuteride. A chain mechanism is proposed to explain the much more rapid exchange of RuH/D-2 than RuCO exchange with (CO)-C-13.

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