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Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)(2){BiCl2}]

  作者 BRAUNSCHWEIG HOLGER; BRENNER PETER; COGSWELL PAUL; KRAFT KATHARINA; SCHWAB KATRIN  
  选自 期刊  Chemical Communications;  卷期  2010年46-42;  页码  7894-7896  
  关联知识点  
 

[摘要]The synthesis and full characterisation of trans-[PtCl(PCy3)(2){BiCl2}] is reported via the oxidative addition of the bismuth-chloride bond across [Pt(PCy3)(2)]; this represents the first instance of such an oxidative addition reaction to be undertaken by a bismuth halide bond.

 
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