Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)Re-v-Oxo Complexes

[摘要]：The development and application of chiral, non-racemic Re-v-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.

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