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Synthesis and Structural Characterization of a New Class of Strong Chiral Bronsted Acids: 1,1 '-Binaphthyl-2,2 '-bis(sulfuryl)imides (JINGLEs)

  作者 BERKESSEL ALBRECHT; CHRIST PHILIPP; LECONTE NICOLAS; NEUDOERFL JOERGM; SCHAEFER MATHIAS  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2010年-27;  页码  5165-5170  
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[摘要]We herein present the first synthesis of 1,1'-binaphthy1-2,2'-bis(sulfuryl)imides (JINGLEs). This new class of chiral Bronsted acids was synthesized in one step from the corresponding BINOLs and imidobis(sulfuryl chloride). A total of six enantiopure 1,1'-binaphthyl-2,2'-bis(sulfuryl)imides, carrying different 3,3'-substituents, were synthesized and characterized, inter alia, by X-ray crystallography.

 
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