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Practical Approach to Structurally Diverse Monoimine Salts and Nonsymmetrical Metallosalphen Complexes

  作者 ESCUDEROADAN EDUARDO C; MARTINEZ BELMONTE MARTA; BENETBUCHHOLZ JORDI; KLEIJ ARJAN W  
  选自 期刊  Organic Letters;  卷期  2010年12-20;  页码  4592-4595  
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[摘要]A practical approach toward the synthesis of monoimme NBu4 salts derived from Zn(salphen) complexes is described The method involves nucleophilic addition of the hydroxide anion to the imine bond followed by hydrolysis These monoimines provide accessible and useful reagents for the synthesis of (chiral) metallosalens with fine-tunable properties

 
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