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Halofluorination of Alkenes Using Trihaloisocyanuric Acids and HF center dot Pyridine

  作者 CRESPO LIVIA T C; RIBEIRO RODRIGO DA S; DE MATTOS MARCIO C S; ESTEVES PIERRE M  
  选自 期刊  Synthesis;  卷期  2010年-14;  页码  2379-2382  
  关联知识点  
 

[摘要]Halofluorination of alkenes with a new system (trihaloisocyanuric acids and HF center dot pyridine) results in the formation of vicinal halofluoroalkanes. The reaction is regioselective leading to Markovnikov-oriented products and the halofluorinated adducts follow anti-addition in the case of cyclohexene and 1-methylcyclohexene. Reaction yields range from 67-88%.

 
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