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Metal-Free Synthesis of N-Cyano-Substituted Sulfilimines and Sulfoximines

  作者 PANDEY ANKUR; BOLM CARSTEN  
  选自 期刊  Synthesis;  卷期  2010年-17;  页码  2922-2925  
  关联知识点  
 

[摘要]Starting from the corresponding sulfides, N-cyano sulfoximines can easily be accessed under metal-free conditions via the corresponding N-cyano-substituted sulfilimines. The reaction sequence involves a sulfide imination with cyanogen amide in presence of a base and N-bromosuccinimide (NBS) followed by an m-chloroperoxybenzoic acid (MCPBA) mediated oxidation of the resulting sulfilimine intermediates.

 
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