Stereoselectiye Total Synthesis of Goniothalesdiol A via Chiron Approach

[摘要]：The stereocontrolled synthesis of goniothalesdiol A. a dihydroxylated tetrahydropyran compound, has been accomplished using D-ribose as chiral precursor. The key steps involved are aryl Grignard reaction, stereoselective alkoxy-directed keto reduction, and intramolecular oxy-Michael addition.

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