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o-Benzenedisulfonimide as a Powerful and Recyclable Organocatalyst for the Nazarov Reaction

  作者 BARBERO MARGHERITA; CADAMURO SILVANO; DEAGOSTINO ANNAMARIA; DUGHERA STEFANO; LARINI PAOLO; OCCHIATO ERNESTO G; PRANDI CRISTINA; TABASSO SILVIA; VULCANO ROSARIA; VENTURELLO PAOLO  
  选自 期刊  Synthesis;  卷期  2009年-13;  页码  2260-2266  
  关联知识点  
 

[摘要]o-Benzenedisulfonimide has been used for the first time as a Bronsted acid catalyst to induce electrocyclization of dienones into cyclopentenones (Nazarov reaction). The catalyst has been used in various organic solvents or under solvent-free conditions and it is entirely recoverable from the reaction mixture. The versatility and the effectiveness of the proposed procedure is demonstrated on a wide range of both activated and inactivated substrates.

 
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