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A Facile Synthesis of Two Series of Multifunctional Carbon Compounds from alpha,alpha-Dihalo Ketones Using Allylsamarium Bromide

  作者 LIU XIAODAN; ZHANG SONGLIN; DI JUCAI  
  选自 期刊  Synthesis;  卷期  2009年-16;  页码  2749-2755  
  关联知识点  
 

[摘要]The use of allylsamarium bromide to effect two different reactions on the common starting material, alpha,alpha-dihalo ketones, is presented. With DMT, alpha-halo-alpha-allyl aldehydes were obtained, while alpha-hydroxy-alpha-allyl aldehyde acetals were obtained in the presence of NaOMe/McOH

 
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