Chemistry of Polyhalogenated Nitrobutadienes, Part 7: A Novel Synthetic Access to Chlorinated Nitrile Oxides

[摘要]：Reaction of gem-dichloronitroalkenes with base leads to the formation of chlorinated nitrile oxides, probably via a cyclic intermediate. The 1,3-dipoles can be trapped with alkenes to give dihydroisoxazoles with a chlorinated side chain in 3-position. This novel synthetic method is fairly general.

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