Bimetallic Palladium-Platinum-on-Carbon-Catalyzed H-D Exchange Reaction: Synergistic Effect on Multiple Deuterium Incorporation

[摘要]：We prepared several activated carbon-supported bimetallic Pd-Pt catalysts (Pd-Pt/C) by using various reducing reagents, and examined their catalytic activities for the deuteration of alkyl-substituted aromatic compounds. Multiple deuterations catalyzed by Pt-Pd/C proceeded in D2O at 180 degrees C under a H-2 atmosphere, and a synergistic effect was observed in relation to the incorporation of deuterium at sterically hindered positions on aromatic rings.

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