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On the Synthesis of Asymmetric and Dissymmetric Amino Analogues of Troger's Base

  作者 ARTACHO JOSEP; WARNMARK KENNETH  
  选自 期刊  Synthesis;  卷期  2009年-18;  页码  3120-3126  
  关联知识点  
 

[摘要]Monoamino and diamino analogues of Troger's base have been synthesized by palladium-catalyzed aminations of the corresponding dihalo analogues using low catalyst loadings. Depending on the nature of the dihalo analogue (Br or 1). catalyst loading and the scale of the reaction, monoamino-monohalo and/or diamino analogues of Troger's base were obtained.

 
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