Ethyl 2-(Diisopropoxyphosphoryl)-2H-azirine-3-carboxylate: Reactions with Nucleophilic 1,3-Dienes

[摘要]：Ethyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate, the First example of an azirine bearing simultaneously ester and phosphonate groups was generated in situ and reacted with a number of 1,3-dienes. Cycloadducts or their ensuing rearranged products were isolated in moderate yields.

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