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Copper(II)-Catalyzed Esterification of Arenecarboxylic Acids with Aryl- and Vinyl-Substituted Trimethoxysilanes

  作者 LUO FANG; PAN CHANDUO; QIAN PENGCHENG; CHENG JIANG  
  选自 期刊  Synthesis;  卷期  2010年-12;  页码  2005-2010  
  关联知识点  
 

[摘要]In this paper, the copper(II)-catalyzed esterification reaction of arenecarboxylic acids with aryl- or vinyl-substituted trimethoxysilanes is described. A series of aryltrimethoxysilanes and arenecarboxylic acids worked well under this procedure, affording aryl benzoate derivatives in moderate to good yields. Notably, trimethoxy(vinyl)silanes also worked well under this procedure giving a facile and versatile method to access vinyl benzoate derivatives.

 
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