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Cyclopentadienylcobalt-Mediated Intermolecular Cycloaddition of alpha,omega-Diynes to (Cyclo)alkenes: Synthesis of Linearly Fused Oligocycles and Extension to Enantiomerically Pure (6aR,10aR)-Dihydroanthracyclinones

  作者 AUBERT CORINNE; GANDON VINCENT; HAN SANGDON; JOHNSON BARRY M; MALACRIA MAX; SCHOEMENAUER STEN; VOLLHARDT K PETER C; WHITENER GLENN D  
  选自 期刊  Synthesis;  卷期  2010年-13;  页码  2179-2200  
  关联知识点  
 

[摘要]The generality of the [CpCoL2]-mediated [2+2+2] cycloaddition of alpha,omega-diynes to (cyclo)alkenes has been extended to include linear oligocycles as models for the one-step, A + D -> ABCD construction of optically pure, novel 6,10-dihydroanthracyclinones.

 
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