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Oxidative Cyclization of 3-Cinnamoyltropolones with I-2/DMSO/H2SO4 System

  作者 GAO WENTAO; LI YANG; ZHANG HONG; CHANG MINGQIN; IMAFUKU KIMIAKI  
  选自 期刊  Journal of Heterocyclic Chemistry;  卷期  2009年46-6;  页码  1107-1112  
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[摘要]In this study, a facile and general method synthesizing flavone-like 2-aryl-4,9-dihydrocyclohepta[b]-pyran-4,9-diones (2a-y) from 3-cinnamoyltropolones (1a-y) via oxidative cyclization reaction by using I-2/DMSO/H2SO4 system is described. The method was found to be successfully applicable to a wide range of 3-cinnamoyltropolone derivatives and characterized by generality, compatibility, and easy work-up procedures.

 
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