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Synthesis of alpha,beta-Unsaturated Caprolactams Starting from Heterocyclic Imines

  作者 JOHANNES KATHARINA; WATZKE MARTIN; MARTENS JUERGEN  
  选自 期刊  Journal of Heterocyclic Chemistry;  卷期  2010年47-3;  页码  697-702  
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[摘要]New classes of alpha,beta-unsaturated caprolactams containing variable heteroatoms in delta-position were synthesized from heterocyclic imines as a starting material. The synthetic route is based on an acid chloride addition followed by a ring-closing metathesis using a ruthenium catalyst.

 
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