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On the Reaction of 3-Cyanochromones with Phenyl- and Methylhydrazines: Structural Revision and a Simple Synthesis of Chromeno[4,3-c]pyrazol-4-Ones

  作者 SOSNOVSKIKH VYACHESLAV YA; MOSHKIN VLADIMIR S; KODESS MIKHAIL I  
  选自 期刊  Journal of Heterocyclic Chemistry;  卷期  2010年47-3;  页码  629-633  
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[摘要]Reactions of 3-cyanochromones with phenylhydrazine gave the corresponding 5-amino-4-salicyloyl-1-phenylpyrazoles, 2-aminochromone-3-carbaldehyde N-phenylhydrazones, and 1-phenylchromeno[4,3-c]pyrazol-4(1H)-one, depending on the reaction conditions. With methylhydrazine, 3-(2-hydroxyaryl)-1-methylpyrazole-4-carbonitriles and 2-methylchromeno[4,3-c]pyrazol-4(2H)-ones were obtained in moderate to high yields.

 
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