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[摘要]：Development and synthetic application of epoxysilane rearrangement, a novel synthetic use of alpha,beta-epoxysilanes, in which an anion-induced ring-opening of epoxide and Brook rearrangement in the resulting alpha-silyl alkoxide occur in a tandem fashion to provide a beta-siloxy allyl anion, are described. Chirality transfer from epoxides to the position next to a nitrile group by taking advantage of the concerted process of the rearrangement is also reported. |
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