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ORGANOCATALYTIC ASYMMETRIC DIELS-ALDER REACTION OF FURAN UNDER HIGH PRESSURE

  作者 MIMOTO AKIKO; NAKANO KEIJI; ICHIKAWA YOSHIYASU; KOTSUKI HIYOSHIZO  
  选自 期刊  Heterocycles;  卷期  2010年80-2;  页码  799-804  
  关联知识点  
 

[摘要]A new method for the asymmetric Diels-Alder reaction between furan and acrolein has been developed through the combined use of chiral organocatalysts and high pressure (yield up to 91%; endo-adduct up to 19% ee, exo-adduct up to 26% ee).

 
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