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A SYNTHESIS OF beta-ALLYL SUBSTITUTED ISOTETRONIC ACID DERIVATIVES VIA THERMAL CLAISEN REARRANGEMENT

  作者 MA XIAPING; LI ZHIMING; WANG QUANRUI  
  选自 期刊  Heterocycles;  卷期  2010年81-6;  页码  1485-1491  
  关联知识点  
 

[摘要]Isotetronic acids are of great interest in agricultural and pharmacological research and occur in a number of natural products. This paper describes the first Claisen rearrangement of the O-allyl substituted isotetronic acids 2 under thermal conditions furnishing the beta-allyl substituted isotetronic acid derivatives 3 in high yields.

 
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