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Tandem Oxidation/Rearrangement of beta-Ketoesters to Tartronic Esters with Molecular Oxygen Catalyzed by Calcium Iodide under Visible Light Irradiation with Fluorescent Lamp

  作者 KANAI NAOHIKO; NAKAYAMA HIROKI; TADA NORIHIRO; ITOH AKICHIKA  
  选自 期刊  Organic Letters;  卷期  2010年12-9;  页码  1948-1951  
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[摘要]It was found that beta-ketoesters were directly transformed to the corresponding alpha-hydroxymalonic esters, tartronic esters, with molecular oxygen catalyzed by calcium iodide under visible light irradiation from fluorescent lamp. This reaction includes tandem oxidation/rearrangement and has received much attention from the viewpoint of reduction of energy consumption, labor, and solvents.

 
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