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Lewis Acid Catalyzed Cycloaddition of Methylenecyclopropanes with Salicylaldehydes

  作者 JIANG MIN; SHI MIN  
  选自 期刊  Organic Letters;  卷期  2010年12-11;  页码  2606-2609  
  关联知识点  
 

[摘要]Lewis acid catalyzed cycloaddition of methylenecyclopropanes (MCPs) with o-quinonemethide analogues, derived from the corresponding salicylaldehydes and CH(OEt)(3), produces the corresponding cycloadducts 3 in moderate to high yields at room temperature (20 degrees C). Moreover, the compounds 3 can be transformed to the indene derivatives 5 at high temperature. Plausible mechanisms have been proposed on the basis of control experiments.

 
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