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Gold-Catalyzed Benzannulation of 3-Alkoxy-1,5-enynes: Access to Functionalized Benzenes

  作者 LI GUIJIE; LIU YUANHONG  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-9;  页码  2903-2909  
  关联知识点  
 

[摘要]A cationic Au(I) complex catalyzed benzannulation of 3-alkoxy-1,5-enynes bridged by a cyclopropyl ring with a variety of nucleophiles is described. The reaction occurs selectively through a 6-endo-dig pathway to provide tri- and tetrasubstituted benzenes efficiently under mild reaction conditions.

 
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