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Synthesis of Polyhalogenated 2-(Phenylamino)pyridines by Thermal Amination Reactions

  作者 WALDVOGEL SIEGFRIED R; FAUST ANDREAS; BARKMANN WERNER; FROEHLICH ROLAND; WOLFF OLIVER  
  选自 期刊  Synthesis;  卷期  2009年-10;  页码  1651-1654  
  关联知识点  
 

[摘要]Animation reactions of 2,6-dibrornopyridine with a variety of halogenated anilines were achieved thermally when 2,2,6,6-tetramethylpiperidine was employed as an auxiliary base. The solvent-free thermal conversion was superior to palladium-catalyzed transformations of such Substrates since no high-molecular-weight byproducts were observed.

 
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