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[摘要]:Recyclable TEMPO-functionalized polyethylene glycol [PEG(6000)-(TEMPO)(2)] in combination with cuprous chloride were developed for biomimetic oxidation of a series of benzylic, allylic, heterocyclic alcohols, and 2-phenylethanol into the corresponding aldehydes or ketones in high selectivity and in moderate to high conversion in compressed CO2, which enhanced the catalytic activity as well as improved the selectivity. |
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