Oxo-Diels-Alder Reaction of Danishefsky's Diene with Aldehydes, Catalyzed by Chiral Tridentate Chromium(III)-Schiff Base Complexes

[摘要]：The enantioselective hetero-Diels-Alder reaction of Danishefsky's diene with simple aromatic and aliphatic aldehydes is catalyzed by chiral tridentate Schiff base-chromium(III) complexes. In many cases, 2,3-dihydropyran-4-ones are obtained in good yields (up to 99%) and high enantioselectivities (up to 97%).

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