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Metallic Samarium Promoted Self-Coupling of Baylis-Hillman Adducts to Functionalized 1,5-Hexadienes in the Presence of the I-2/ClCO2Et/BiCl3 System

  作者 BIAN HAISHAN; LI JIAN; LI CHUNJU; WANG GAN; DUAN ZHENG; JIA XUESHUN  
  选自 期刊  SYNLETT;  卷期  2010年-9;  页码  1412-1414  
  关联知识点  
 

[摘要]A facile strategy for the self-coupling of Baylis-Hillman adducts to functionalized 1,5-hexadienes has been described. Promoted by the Sm/I-2/ClCO2Et/BiCl3 system, the present method allows for the conversion of MBH adducts to their corresponding 1,5-hexadienes.

 
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