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Design and Regioselective Synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl Acrylates as Inimers for Hyperbranched (Co)Polyacrylates

  作者 PUGH COLEEN; RAVEENDRA BINDU; SINGH ANIRUDHA; SAMUEL REICHEL; GARCIA GUILLERMINA  
  选自 期刊  SYNLETT;  卷期  2010年-13;  页码  1947-1950  
  关联知识点  
 

[摘要]A route based on deaminohalogenation of serine is established to synthesize bromoinimers that can be homopolymerized to produce hyperbranched polyacrylates that are true architectural analogues of linear polyacrylates; that is, an ester group is attached to every other carbon along the polymer backbone, and each repeat unit contains a free ester side chain.

 
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