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Structure and Electronic Properties of Graphene Nanoislands on Co(0001)

  作者 Eom, D; Prezzi, D; Rim, KT; Zhou, H; Lefenfeld, M; Xiao, S; Nuckolls, C; Hybertsen, MS; Heinz, TF; Flynn, GW  
  选自 期刊  Nano Letters;  卷期  2009年9-8;  页码  2844-2848  
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[摘要]We have grown well-ordered graphene adlayers on the lattice-matched Co(0001) surface, Low-temperature scanning tunneling microscopy measurements demonstrate an on-top registry of the carbon atoms with respect to the Co(0001) surface. The tunneling conductance spectrum shows that the electronic structure is substantially altered from that of isolated graphene, implying a strong coupling between graphene and cobalt states. Calculations using density functional theory confirm that structures with on-top registry have the lowest energy and provide clear evidence for strong electronic coupling between the graphene pi-states and Co d-states at the interface.

 
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