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Defect-induced Photoluminescence from Dark Excitonic States in Individual Single-Walled Carbon Nanotubes

  作者 Harutyunyan, H; Gokus, T; Green, AA; Hersam, MC; Allegrini, M; Hartschuh, A  
  选自 期刊  Nano Letters;  卷期  2009年9-5;  页码  2010-2014  
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[摘要]We show that new low-energy photoluminescence (PL) bands can be created in the spectra of semiconducting single-walled carbon nanotubes by intense pulsed excitation. The new bands are attributed to PL from different nominally dark excitons that are "brightened" because of a defect-induced mixing of states with different parity and/or spin. Time-resolved PL studies on single nanotubes reveal a significant reduction of the bright exciton lifetime upon brightening of the dark excitons. The lowest-energy dark state has longer lifetimes and is not in thermal equilibrium with the bright state.

 
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