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Chemoselective etherification of benzyl alcohols using 2,4,6-trichloro-1,3,5-triazine and methanol or ethanol catalyzed by dimethyl sulfoxide.

  作者 Sun, Lili;Guo, Yuping;Peng, Guisheng;Li, Chunbao;  
  选自 期刊  Synthesis;  卷期  2008年-21;  页码  3487-3491  
  关联知识点  
 

[摘要]An efficient method for the transformation of benzyl alcs. into their Me or Et ethers was established using 2,4,6-trichloro-1,3,5-triazine (TCT) and DMSO in MeOH or EtOH. This procedure chemoselectively converts benzylic OH into the corresponding Me or Et ethers in the presence of aliph. or phenolic OH.

 
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