【文章名】Cross-metathesis of chiral N-tert-butylsulfinyl homoallylamines: application to the enantioselective synthesis of naturally occurring 2,6-cis-disubstituted piperidines.
Cross-metathesis of chiral N-tert-butylsulfinyl homoallylamines: application to the enantioselective synthesis of naturally occurring 2,6-cis-disubstituted piperidines.
作者
Gonzalez-Gomez, Jose C.;Foubelo, Francisco;Yus, Miguel;
[摘要]：The synthesis of the piperidine alkaloids (+)-dihydropinidine, (+)-isosolenopsin, (+)-isosolenopsin A, and (2R,6R)-6-methylpipecolate, based on cross-metathesis of chiral N-tert-butylsulfinyl homoallylamines with Me vinyl ketone, is presented.
