Syntheses of the P-methylase substrates of the bialaphos biosynthetic pathway.

[摘要]：N-AcDMPTT) is the substrate for the P-methylation reaction in the biosynthesis of phosphinothricin tripeptide (PTT), which is widely used as an herbicide. To study the mechanism for this unique P-methylation reaction catalyzed by the BcpD protein and the functions of the unusual nonribosomal peptide synthetases involved in PTT biosynthesis, the chem. syntheses of I and II is reported.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内