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Formation and Utility of Azasilacyclopentadienes Derived from Silacyclopropenes and Nitriles.

  作者 Anderson, Laura L.;Woerpel, K. A.;  
  选自 期刊  Organic Letters;  卷期  2009年11-2;  页码  425-428  
  关联知识点  
 

[摘要]converted to allylic amines after redn. and protodesilylation. The enamine functionality of azasilacyclopentadienes also participates in 1,4-addn. reactions and undergoes a hydroboration and oxidn. sequence to form an allylic 1,2-amino alc.

 
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