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Iron-catalyzed 1,4-addition of a-olefins to dienes.

  作者 Moreau, Benoit;Wu, Jessica Y.;Ritter, Tobias;  
  选自 期刊  Organic Letters;  卷期  2009年11-2;  页码  337-339  
  关联知识点  
 

[摘要]A intermol., stereo- and regioselective iron-catalyzed 1,4-addn. of a-olefins to 1,3-dienes using as low as 1 mol % of an iminopyridine-ferrous chloride complex was developed. Importantly, both double bonds of the linear 1,4-diene addn. products are obtained with abs. stereocontrol.

 
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