【文章名】Amide-directed alkenylation of sp2 C-H bonds catalyzed by a cationic Rh(I)/BIPHEP complex under mild conditions: dramatic rate acceleration by a 1-pyrrolidinecarbonyl group.
Amide-directed alkenylation of sp2 C-H bonds catalyzed by a cationic Rh(I)/BIPHEP complex under mild conditions: dramatic rate acceleration by a 1-pyrrolidinecarbonyl group.
[摘要]：A cationic rhodium(I)/BIPHEP complex catalyzes amide-directed regioselective alkenylations of olefinic or arom. sp2 C-H bonds in good yields under mild reaction conditions. The use of a 1-pyrrolidinecarbonyl group as a directing group dramatically accelerates the reaction.
