Toward the Total Synthesis of the Brasilinolides: Construction of a Differentially Protected C20-C38 Segment.
[摘要]:addns. and ketone redns. were employed to construct the two related stereotetrads, while a sequence of Horner-Wadsworth-Emmons (HWE) coupling, CBS redn., and Sharpless AE installed the epoxy alc. functionality.
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