Enantioselective Total Synthesis of Aspergillide C.

[摘要]：The first enantioselective total synthesis of aspergillide C (I), a cytotoxic 14-membered macrolide isolated from the marine-derived fungus Aspergillus ostianus, has been accomplished from a com. available chiral glycidol deriv. by a 12-step sequence involving an expeditious prepn. of a cyclic acetal intermediate and a trans-selective Ferrier-type two-carbon homologation reaction.

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