Synthesis of (+)- and (-)-Monanchorin.
[摘要]:azide, and reaction of the amine with MeSC(NBoc)NHBoc, AgNO3, and Et3N. Treatment of the protected guanidino alc. with 9:1 CDCl3/TFA afforded monanchorin III, whose abs. stereochem. was assigned as shown.
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