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A Molecular Cage-Based [2]Rotaxane That Behaves as a Molecular Muscle.

  作者 Chuang, Chun-Ju;Li, Wan-Sheung;Lai, Chien-Chen;Liu, Yi-Hung;Peng, Shie-Ming;Chao, Ito;Chiu, Sheng-Hsien;  
  选自 期刊  Organic Letters;  卷期  2009年11-2;  页码  385-388  
  关联知识点  
 

[摘要]A mol. cage-based [2]rotaxane that functions as an artificial mol. muscle through the control of the addn. and removal of fluoride anions is reported. The percentage change in mol. length of the [2]rotaxane is ~36% between the stretched and contracted states, which is larger than the percentage change (~27%) in human muscle.

 
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