Controlled self-assembly of nucleotide-lanthanide complexes: specific formation of nanofibers from dimeric guanine nucleotides.

[摘要]：Supramol. nano-architectures were spontaneously formed upon mixing Tb3+ with dNMP or dN2MP nucleotides representing all four nucleobases. Monomeric and dimeric guanine nucleotides monophosphate spontaneously self-assemble into nanoparticles and nanofibers in the presence of lanthanide ions (Tb3+), which reflects differences in the unit coordination structures and their hierarchical assembly.

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