Oxidation leading to reduction: redox-induced electron transfer (RIET).

[摘要]：A review; redox paradox The initial one-electron oxidn. of a metal ion induce a multi-electron rearrangement, leading to oxidn. of the second metal ion and redn. of the tetraoxolate dianionic ligand bridging the two metals. These electron-transfer events were obsd. with numerous spectroscopic, electrochem., and crystallog. methods (TpyA = tris(2-pyridylmethylamine).

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